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Home>Water University>Water Contaminants>1,2,4-Trichlorobenzene

1,2,4-Trichlorobenzene


This is a fact sheet about a chemical that may be found in some public or private drinking water supplies. It may cause health problems if found in amounts greater than the health standard set by the United States Environmental Protection Agency (EPA).

What is 1,2,4-Trichlorobenzene and how is it used?

1,2,4-Trichlorobenzene (1,2,4-TCB) is an aromatic, colorless organic liquid. The greatest use of 1,2,4-trichlorobenzene is primarily as a dye carrier. It is also used to make herbicides and other organic chemicals; as a solvent; in wood preservatives; in abrasives. It was once used as a soil treatment for termite control.

The list of trade names given below may help you find out whether you are using this chemical at home or work.

Trade Names and Synonyms:

Hostetex L-PEC
Trichlorobenzol

Why is 1,2,4-Trichlorobenzene being regulated?

In 1974, Congress passed the Safe Drinking Water Act. This law requires EPA to determine safe levels of chemicals in drinking water which do or may cause health problems. These non-enforceable levels, based solely on possible health risks and exposure, are called Maximum Contaminant Level Goals.

The MCLG for 1,2,4-trichlorobenzene has been set at 0.07 parts per million (ppm) because EPA believes this level of protection would not cause any of the potential health problems described below.

Based on this MCLG, EPA has set an enforceable standard called a Maximum Contaminant Level (MCL). MCLs are set as close to the MCLGs as possible, considering the ability of public water systems to detect and remove contaminants using suitable treatment technologies.

The MCL has also been set at 0.07 ppm because EPA believes, given present technology and resources, this is the lowest level to which water systems can reasonably be required to remove this contaminant should it occur in drinking water.

These drinking water standards and the regulations for ensuring these standards are met, are called National Primary Drinking Water Regulations. All public water supplies must abide by these regulations.

What are the health effects?

Short-term: EPA has found 1,2,4-trichlorobenzene to potentially cause the following health effects when people are exposed to it at levels above the MCL for relatively short periods of time: changes in liver, kidneys and adrenal glands.

Long-term: 1,2,4-Trichlorobenzene has the potential to cause the following effects from a lifetime exposure at levels above the MCL: increased adrenal gland weights.

How much 1,2,4-Trichlorobenzene is produced and released to the environment?

Current production figures on 1,2,4-trichlorobenzene are not available. EPA estimated 1983 production to be in the range of 3 to 8 million lbs., with imports over 3 million lbs. Major environmental releases of 1,2,4-trichlorobenzene are due to its manufacture and use as a dye carrier.

From 1987 to 1993, according to EPA's Toxic Chemical Release Inventory, 1,2,4-trichlorobenzene releases to land and water totalled over 180,000 lbs. These releases were primarily from textile finishing industries. The largest releases occurred in North Carolina and Virginia.

What happens to 1,2,4-Trichlorobenzene when it is released to the environment?

1,2,4-Trichlorobenzene (1,2,4-TCB) binds well to the soil and therefore will not leach appreciably to the groundwater when released to land. However, 1,2,4-TCB has been detected in some groundwater samples which indicates that it can be transported there by some process. If released to water it will largely evaporate within a few hours. It has some potential to accumulate in fish.

How will 1,2,4-Trichlorobenzene be detected in and removed from my drinking water?

The regulation for 1,2,4-trichlorobenzene became effective in 1994. Between 1993 and 1995, EPA required your water supplier to collect water samples every 3 months for one year and analyze them to find out if 1,2,4-trichlorobenzene is present above 0.5 ppb. If it is present above this level, the system must continue to monitor this contaminant.

If contaminant levels are found to be consistently above the MCL, your water supplier must take steps to reduce the amount of 1,2,4-trichlorobenzene so that it is consistently below that level. The following treatment methods have been approved by EPA for removing 1,2,4-trichlorobenzene: Granular activated charcoal in combination with Packed Tower Aeration.

How will I know if 1,2,4-Trichlorobenzene is in my drinking water?

If the levels of 1,2,4-trichlorobenzene exceed the MCL, 0.07 ppm, the system must notify the public via newspapers, radio, TV and other means. Additional actions, such as providing alternative drinking water supplies, may be required to prevent serious risks to public health.

This is a factsheet about a chemical that may be found in some public or private drinking water supplies. It may cause health problems if found in amounts greater than the health standard set by the United States Environmental Protection Agency (EPA).

Drinking Water Standards:

Mclg: 0.07 ppm (parts per million)

Mcl: 0.07 ppm



1,2,4-Trichlorobenzene Releases to Water and Land, 1987 to 1993 (in pounds):

Water Land
TOTALS (in pounds) 157,541 22,835

Top Five States*
NC 80,253 13,209
VA 36,970 0
GA 17,639 8,951
WV 20,300 0
NY 1,150 1

Major Industries*
Finishing plants, misc 52,249 0
Finishing plants, synth. 47,976 0
Weaving, finishing mills 20,139 8,951
Alkalies, chlorine 21,773 1
Knitting mills, misc 9,077 9,994
Knit outerwear mills 1,300 3,200


* Water/Land totals only include facilities with releases greater than 100 lbs.

Note: This fact sheet is part of a larger publication adapted from U.S. EPA publication: EPA National Primary Drinking Water Regulations.